釩(Vanadium)是一(yi)種金屬(shu)元素,元素符號為(wei)V,銀灰色金屬(shu),在元素周期(qi)表中屬(shu)VB族(zu),原子序(xu)數(shu)23,原子量(liang)50.9414,體心(xin)立方晶體,常見化合價為(wei)+5、+4、+3、+2。釩的(de)(de)熔(rong)(rong)點很高(gao),為(wei)難熔(rong)(rong)金屬(shu),有延展性(xing),質堅硬,無磁性(xing)。具(ju)有耐(nai)鹽(yan)酸(suan)和硫酸(suan)的(de)(de)本(ben)領,并(bing)且在耐(nai)氣、耐(nai)鹽(yan)、耐(nai)水(shui)腐蝕(shi)的(de)(de)性(xing)能要比大(da)多數(shu)不銹鋼(gang)好。
釩(fan)先后被(bei)兩次發現。第(di)一(yi)次是在(zai)(zai)1801年由墨西哥城的(de)(de)(de)礦(kuang)(kuang)物(wu)學(xue)教(jiao)授節烈(lie)里瓦發現的(de)(de)(de)。他發現它(ta)在(zai)(zai)亞釩(fan)酸鹽樣本(ben)中(zhong),這個樣本(ben)就是Pb5(VO4)3Cl,由于這種(zhong)新(xin)元素(su)的(de)(de)(de)鹽溶液在(zai)(zai)加熱時呈現鮮(xian)艷的(de)(de)(de)紅色,所(suo)(suo)以被(bei)取名(ming)為“愛麗特羅尼”,即“紅色”的(de)(de)(de)意思,并將這種(zhong)物(wu)品(pin)送到巴黎。然(ran)而(er),法國化學(xue)家推(tui)斷它(ta)是一(yi)種(zhong)被(bei)污染的(de)(de)(de)鉻(ge)礦(kuang)(kuang)石,所(suo)(suo)以沒有被(bei)人(ren)們公認。
第(di)二(er)次發現是(shi)在(zai)1830年(nian),瑞典化學家(jia)塞(sai)夫斯(si)(si)(si)特倫(lun)(Sefstrom.N.G,1787-1845)在(zai)研(yan)究(jiu)斯(si)(si)(si)馬蘭礦(kuang)(kuang)區的(de)鐵礦(kuang)(kuang)時,用酸溶解鐵,在(zai)殘渣中發現了釩(fan)。因為(wei)(wei)釩(fan)的(de)化合物的(de)顏(yan)色五顏(yan)六色,十分漂亮(liang),所以就用北歐神話中一位叫凡娜迪絲“Vanadis”的(de)美麗女神的(de)名字(zi)給這種(zhong)新元(yuan)素(su)起名叫“Vanadium”。中文按其譯音定名為(wei)(wei)釩(fan)。塞(sai)夫斯(si)(si)(si)特倫(lun)、維勒(le)、貝采里烏斯(si)(si)(si)等人(ren)都(dou)曾研(yan)究(jiu)過釩(fan),確認釩(fan)的(de)存在(zai),但他(ta)們始終沒有分離出單(dan)質釩(fan)。后(hou)來到了1830年(nian)寫佛寺特勒(le)木(mu)在(zai)由(you)瑞典鐵礦(kuang)(kuang)石提煉出的(de)鐵中發現了它,并肯定這是(shi)一種(zhong)新元(yuan)素(su)稱之為(wei)(wei)釩(fan),他(ta)能夠證(zheng)明它是(shi)一種(zhong)新的(de)元(yuan)素(su),并因此擊敗了一位與他(ta)競爭的(de)化學家(jia),來自在(zai)錫馬潘(墨西哥)的(de)沃勒(le)(Friedrich W?hler),他(ta)也在(zai)對另一種(zhong)釩(fan)礦(kuang)(kuang)石進行研(yan)究(jiu)。
1840年,俄羅斯礦(kuang)物(wu)工程(cheng)師(shi)蘇賓(bin)寫道“含(han)銅生鐵、黑銅、銅錠是(shi)含(han)釩(fan)合金(jin),由于釩(fan)的存在,使(shi)它們具有(you)較高的硬度”。
1869年英(ying)國化(hua)(hua)學家(jia)羅斯科(ke)(Roscoe.H.E,1833-1915)用氫氣(qi)還原二氧化(hua)(hua)釩(fan),才第一(yi)次(ci)制得了純凈的金屬釩(fan),而(er)且他證明(ming)了之前的金屬樣本其實(shi)是氮化(hua)(hua)釩(fan)(VN)。
1939年(nian),在俄羅(luo)斯的(de)(de)彼爾姆斯克的(de)(de)含銅砂巖中也發現了(le)釩。
在發現(xian)釩這種金屬后(hou),人們(men)慢慢了解到(dao)了它的(de)性質(zhi),并開始將它應用(yong)到(dao)人們(men)的(de)生(sheng)活當(dang)中。1882年(nian),英國列·克魯佐特(te)鋼鐵(tie)公司用(yong)含釩1.1%的(de)煉(lian)鋼爐渣制得釩的(de)磷酸鹽,年(nian)產量約60t。用(yong)戶是生(sheng)產苯(ben)胺黑的(de)染料廠。
在19世紀末20世紀初,俄羅(luo)斯開始利用碳還原法還原鐵(tie)(tie)和(he)釩氧化(hua)物,首次制備出(chu)釩鐵(tie)(tie)合金(含V35%~40%)。1902~1903年俄羅(luo)斯進(jin)行了鋁熱法制取釩鐵(tie)(tie)的(de)試驗。
1927年(nian),美國的(de)馬(ma)爾登和賴奇用金屬鈣還原五(wu)氧化二(er)釩(V2O5),第一次制得了含(han)釩99.3%~99.8%的(de)可(ke)鍛性金屬釩。
19世紀末,研究還發現了(le)釩在(zai)鋼中能顯著改善鋼材的機械性能,從而使釩在(zai)工業上才(cai)得到廣泛(fan)應用。至(zhi)20世紀初,人們開(kai)始大量開(kai)采釩礦。
世界上生產(chan)釩的(de)礦(kuang)石(shi)主(zhu)要以(yi)釩鈦磁鐵(tie)礦(kuang)為(wei)主(zhu),在俄羅(luo)斯(si)、南非、中國、澳大利亞(ya)及美國等(deng)國家都有(you)豐富的(de)釩鈦磁鐵(tie)礦(kuang)資源(yuan),此外在釩鈾礦(kuang)、鋁土礦(kuang)、磷巖(yan)礦(kuang)、碳(tan)質頁(ye)巖(yan)、石(shi)油(you)燃(ran)燒(shao)灰渣、廢(fei)催化(hua)劑等(deng)均可作為(wei)回收釩的(de)資源(yuan)
釩(fan)的(de)(de)蹤(zong)(zong)跡遍布全(quan)世界。在地(di)(di)殼中(zhong)(zhong),釩(fan)的(de)(de)含量并不少,平均在兩萬個原子中(zhong)(zhong),就有一個釩(fan)原子,比(bi)銅、錫、鋅、鎳的(de)(de)含量都多,但釩(fan)的(de)(de)分布太分散了(le),幾乎沒(mei)有含量較多的(de)(de)礦(kuang)床。在海水中(zhong)(zhong),在海膽等海洋生物體內,在磁鐵礦(kuang)中(zhong)(zhong),在多種(zhong)瀝青礦(kuang)物和(he)煤灰中(zhong)(zhong),在落(luo)到(dao)地(di)(di)球的(de)(de)隕石和(he)太陽的(de)(de)光(guang)譜線中(zhong)(zhong),人們都發現了(le)釩(fan)的(de)(de)蹤(zong)(zong)影。釩(fan)是地(di)(di)球上(shang)廣泛分布的(de)(de)微量元(yuan)素,其(qi)含量約占地(di)(di)殼構成的(de)(de)0.02%,獲取相對容易(yi)。
世界上已知的(de)釩(fan)儲量有98%產于(yu)釩(fan)鈦磁(ci)鐵礦(kuang)。除(chu)釩(fan)鈦磁(ci)鐵礦(kuang)外、釩(fan)資源還部分賦(fu)存(cun)于(yu)磷塊巖(yan)(yan)礦(kuang),含鈾砂巖(yan)(yan),粉砂巖(yan)(yan),鋁土礦(kuang),含碳(tan)質的(de)原油(you)、煤、油(you)頁巖(yan)(yan)及瀝青(qing)砂中。
世(shi)界釩(fan)鈦磁(ci)鐵礦的(de)儲量很大(da),并且集(ji)(ji)中在少數幾個國(guo)(guo)家(jia)和地(di)區(qu),包括(kuo):獨(du)聯(lian)體、美國(guo)(guo)、中國(guo)(guo)、南(nan)(nan)非(fei)、挪(nuo)威、瑞(rui)典(dian)、芬蘭、加拿(na)大(da)、澳(ao)大(da)利亞(ya),并且集(ji)(ji)中分(fen)布(bu)在南(nan)(nan)非(fei)洲、北美洲等地(di)區(qu)。根據1988年美國(guo)(guo)礦業局統計(ji)資料表明,世(shi)界釩(fan)儲量基礎為1.6億噸(以釩(fan)計(ji))。按開采(cai)量計(ji)算,世(shi)界現探(tan)明的(de)釩(fan)資源可(ke)供(gong)開采(cai)150年。從儲量基礎看(kan),南(nan)(nan)非(fei)占(zhan)(zhan)46%,獨(du)聯(lian)體占(zhan)(zhan)23.6%,美國(guo)(guo)占(zhan)(zhan)13.1%,中國(guo)(guo)占(zhan)(zhan)11.6%,其它國(guo)(guo)家(jia)的(de)總(zong)和不足(zu)6%。
在(zai)南非,釩通常在(zai)釩磁(ci)鐵礦的礦層中產生。這些礦層的平均品位為1.5%。據估計,南非釩儲(chu)量約為1250萬噸(dun),世界第一。
礦(kuang)物有釩(fan)酸(suan)鉀鈾礦(kuang)、褐鉛礦(kuang)和綠硫釩(fan)礦(kuang)、石煤礦(kuang)等(deng)。中國是釩(fan)資源比較(jiao)豐富的(de)(de)國家,釩(fan)儲(chu)量為2055萬噸(以V2O5計)主要賦存釩(fan)鈦磁鐵礦(kuang)中,且集(ji)中分布(bu)在四川的(de)(de)攀(pan)枝花市、河北承德市。攀(pan)枝花釩(fan)儲(chu)量為1295萬噸,占(zhan)中國釩(fan)儲(chu)量的(de)(de)63%。
元素在海水(shui)中的含量 0.0016ppm
元素(su)在(zai)太陽中(zhong)的含量 0.4ppm
地(di)殼中含量 160ppm
釩(fan)是一(yi)種銀灰(hui)色的(de)金屬(shu)(shu)。熔點(dian)(dian)1890℃,屬(shu)(shu)于高熔點(dian)(dian)稀(xi)有(you)(you)金屬(shu)(shu)之(zhi)列。它的(de)沸(fei)點(dian)(dian)3380℃,純(chun)釩(fan)質(zhi)堅硬,無磁性,具有(you)(you)延展性,但(dan)是若含有(you)(you)少量(liang)的(de)雜質(zhi),尤(you)其是氮,氧,氫等,能顯著降低其可(ke)塑(su)性。
原子(zi)體積 8.78cm3/mol
相對原子(zi)質量 50.94
莫氏硬度 7
聲音在其中的傳播速率 4560m/s
密度 6.0g/cm3
熔點 1890℃
沸點 3380℃
原子序數 23
質子數 23
電子數 23
晶體結(jie)構:晶胞(bao)為體心立(li)方晶胞(bao),每個(ge)晶胞(bao)含有2個(ge)金(jin)屬原子。
a = 303 pm α = 90°
b = 303 pm β = 90°
c = 303 pm γ = 90°
釩(fan)(fan)的性(xing)質(zhi)(zhi)和(he)(he)(he)鉭以及鈮相似,英(ying)國(guo)化(hua)(hua)學家羅斯(si)科研究了它(ta)的性(xing)質(zhi)(zhi),確定它(ta)與(yu)鉭和(he)(he)(he)鈮相似,這(zhe)為它(ta)們三個在元素周期表中(zhong)(zhong)共建一個分族建立(li)了基(ji)礎。釩(fan)(fan)屬于(yu)中(zhong)(zhong)等(deng)活潑的金屬,化(hua)(hua)合價+2、+3、+4和(he)(he)(he)+5。其中(zhong)(zhong)以+5價為最穩(wen)定,其次是+4價,五價釩(fan)(fan)的化(hua)(hua)合物具(ju)有(you)(you)(you)氧(yang)化(hua)(hua)性(xing)能(neng),低(di)價釩(fan)(fan)則具(ju)有(you)(you)(you)還原性(xing)。釩(fan)(fan)的價態越低(di)還原性(xing)越強。電離能(neng)為6.74eV,具(ju)有(you)(you)(you)耐鹽酸(suan)和(he)(he)(he)硫(liu)酸(suan)的本領,并且在耐氣(qi)、耐鹽、耐水腐蝕的性(xing)能(neng)要(yao)比大(da)多數不銹鋼好。釩(fan)(fan)空(kong)氣(qi)中(zhong)(zhong)不被氧(yang)化(hua)(hua),可溶于(yu)氫氟酸(suan)、硝酸(suan)和(he)(he)(he)王(wang)水。
所屬周期 4
所屬族數 V B
電子層分布 2-8-11-2
電(dian)子層 K-L-M-N
價電子(zi)排布(bu) 3d34s2
氧(yang)化態(tai) -1,+1,+2,+3,+4,+5,
電離能(kJ /mol)
M - M+ 650
M+ - M2+ 1414
M2+ - M3+ 2828
M4+ - M5+ 6294
M5+ - M6+ 12362
M6+ - M7+ 14489
M7+ - M8+ 16760
M8+ - M9+ 19860
M9+ - M10+ 22240
釩能分(fen)別以二、三(san)、四(si)、五價于氧結(jie)合,形成(cheng)四(si)種氧化物(wu):一氧化釩,三(san)氧化二釩,二氧化釩,五氧化二釩。他們的(de)性質(zhi)如下:
化學式 顏(yan)色(se) 密度g/cm3 熔(rong)點℃
VO 灰色 5.23-5.76 1830
V2O3 黑色 4.85 1960
VO2 深(shen)藍色 4.26. 1545
V2O5 紅黃(huang) 3.32 690
高溫下,金屬釩(fan)很容易與(yu)氧和氮(dan)作用。當金屬釩(fan)在空(kong)氣中加熱時,釩(fan)氧化成棕黑(hei)色的三(san)氧化二釩(fan)、深藍色的二氧化釩(fan),并最終(zhong)成為(wei)桔(jie)黃色的五氧化二釩(fan):
釩在氮氣中(zhong)(zhong)(zhong)加熱至(zhi)900~1300℃會生成(cheng)氮化(hua)(hua)釩。釩與碳在高(gao)溫下可生成(cheng)碳化(hua)(hua)釩,但碳化(hua)(hua)反應(ying)(ying)必須(xu)在真空中(zhong)(zhong)(zhong)進行。當釩在真空下或惰性(xing)氣氛中(zhong)(zhong)(zhong)與硅(gui)(gui)、硼、磷、砷(shen)一同(tong)加熱時,可形成(cheng)相應(ying)(ying)的硅(gui)(gui)化(hua)(hua)物、硼化(hua)(hua)物、磷化(hua)(hua)物和(he)砷(shen)化(hua)(hua)物。不同(tong)價(jia)態的釩離子有不同(tong)的顏(yan)色(se):VO2+顏(yan)色(se)為(wei)淺黃色(se)或深綠(lv)色(se),VO2+顏(yan)色(se)為(wei)藍色(se),V3+為(wei)綠(lv)色(se),V2+為(wei)紫色(se)。
我們平常(chang)說的釩(fan)(fan)鹽(yan)是(shi)指這(zhe)幾種(zhong):含有V4+的,含有VO3-的(偏釩(fan)(fan)酸鹽(yan)),含有VO43-的(正(zheng)釩(fan)(fan)酸鹽(yan)),他們包括:偏釩(fan)(fan)酸銨、偏釩(fan)(fan)酸鈉、偏釩(fan)(fan)酸鉀(jia)、正(zheng)釩(fan)(fan)酸鈉、硫酸氧(yang)(yang)釩(fan)(fan)、草酸氧(yang)(yang)釩(fan)(fan)、四氯化釩(fan)(fan)、三(san)氯氧(yang)(yang)釩(fan)(fan)等。
釩(fan)的(de)鹽(yan)類的(de)顏色(se)(se)(se)真(zhen)是(shi)(shi)五光(guang)十色(se)(se)(se),有(you)綠(lv)的(de)、紅的(de)、黑的(de)、黃的(de),綠(lv)的(de)碧(bi)如(ru)翡翠(cui),黑的(de)猶如(ru)濃墨。如(ru)二(er)價(jia)釩(fan)鹽(yan)常呈紫色(se)(se)(se);三價(jia)釩(fan)鹽(yan)呈綠(lv)色(se)(se)(se),四(si)價(jia)釩(fan)鹽(yan)呈淺藍色(se)(se)(se),四(si)價(jia)釩(fan)的(de)堿性衍生(sheng)物常是(shi)(shi)棕(zong)色(se)(se)(se)或(huo)黑色(se)(se)(se),而五氧化二(er)釩(fan)則是(shi)(shi)紅色(se)(se)(se)的(de)。這(zhe)些色(se)(se)(se)彩繽(bin)紛的(de)釩(fan)的(de)化合物,被(bei)制成鮮艷的(de)顏料(liao):把它們加到玻璃中,制成彩色(se)(se)(se)玻璃,也可(ke)以用來制造各種墨水。
釩共有(you)31種同位(wei)素,其中天然存(cun)在的(de)是釩-50和釩-51,其他的(de)全部通(tong)過人工合成。性質如下(xia)表:
符(fu)號(hao) Z(p) N(n) 質量(u) 半(ban)衰期 原子(zi)核自旋(xuan) 相(xiang)對(dui)豐(feng)度 相(xiang)對(dui)豐(feng)度的變(bian)化率(lv)
V-40 23 17 40.01109 2-
V-41 23 18 40.99978 7/2-
V-42 23 19 41.99123 2-
V-43 23 20 42.98065 80ms 7/2-
V-44 23 21 43.97411 111ms (2+)
V-44m 270keV 150ms (6+)
V-45 23 22 44.965776 547ms 7/2-
V-46 23 23 45.9602005 422.50ms 0+
V-46m 801.46keV 1.02ms 3+
V-47 23 24 46.9549089 32.6min 3/2-
V-48 23 25 47.9522537 15.9735d 4+
V-49 23 26 48.9485161 329d 7/2-
V-50 23 27 49.9471585 1.4×10a 6+ 0.0025 0.002487-0.002502
V-51 23 28 50.9439595 穩(wen)定(ding) 7/2- 0.9975 0.997498-0.997513
V-52 23 29 51.9447755 3.743min 3+
V-53 23 30 52.944338 1.60min 7/2-
V-54 23 31 53.94644 49.8s 3+
V-54m 108keV 900ns (5+)
V-55 23 32 54.94723 6.54s (7/2-)
V-56 23 33 55.95053 216ms (1+)
V-57 23 34 56.95256 0.35s (3/2-)
V-58 23 35 57.95683 191ms 3+
V-59 23 36 58.96021 75ms 7/2-
V-60 23 37 59.96503 122ms 3+
V-60m1 150keV 40ms 1+
V-60m2 101keV >400ns
V-61 23 38 60.96848 47.0ms 7/2-
V-62 23 39 61.97378 33.5ms 3+
V-63 23 40 62.97755 17ms (7/2-)
V-64 23 41 63.98347 10ms[>300ns]
V-65 23 42 64.98792 10ms 5/2-
純的(de)金屬釩(fan)一(yi)般是用鉀在高(gao)壓下將五氧化二(er)釩(fan)還原而得到的(de)。大多數釩(fan)是其它(ta)礦物(wu)加工時的(de)副產(chan)品(pin)。工業上也(ye)可(ke)以(yi)以(yi)鋁,焦炭還原五氧化二(er)釩(fan)生產(chan)純釩(fan)。
焦炭還(huan)(huan)原(yuan)五氧(yang)化(hua)二釩生(sheng)產純(chun)釩是將V2O5粉與高純(chun)碳(tan)粉混合(he)均勻,加10%樟(zhang)腦(nao)乙(yi)醚溶液(ye)或酒精,壓塊后(hou)放入(ru)真空(kong)碳(tan)阻爐或感應爐內(nei)。爐內(nei)真空(kong)壓力到6.66×10-1Pa后(hou),升溫(wen)至1573K,保溫(wen)2h。冷卻后(hou)將反應產物破(po)碎。根據(ju)第(di)一次(ci)還(huan)(huan)原(yuan)產物的組(zu)分再配入(ru)適量碳(tan)化(hua)釩或氧(yang)化(hua)釩進行二次(ci)還(huan)(huan)原(yuan)。二次(ci)還(huan)(huan)原(yuan)爐內(nei)的真空(kong)壓力為2.66×10-2Pa,溫(wen)度(du)控制在1973~2023K之間,并保溫(wen)一段時(shi)間。真空(kong)碳(tan)還(huan)(huan)原(yuan)法所得(de)金(jin)屬釩的成分(質量分數m/%)為:釩99.5,氧(yang)0.05,氮0.01,碳(tan)0.1。釩收率可達98%~99%。
鋁(lv)熱還原法(fa)是將五氧化二(er)釩(fan)(fan)和(he)純鋁(lv)放在反應彈進行反應,生成(cheng)釩(fan)(fan)鋁(lv)合(he)金(jin)(jin)(jin)。釩(fan)(fan)合(he)金(jin)(jin)(jin)在2063K的高溫和(he)真空中脫鋁(lv),可(ke)制得含釩(fan)(fan)94%~97%的粗金(jin)(jin)(jin)屬釩(fan)(fan)。
在(zai)(zai)鋼(gang)(gang)(gang)(gang)中加(jia)入百分之(zhi)幾(ji)的(de)釩(fan)(fan)(fan),就能使(shi)鋼(gang)(gang)(gang)(gang)的(de)彈(dan)(dan)性(xing)、強度大增(zeng),抗(kang)磨損(sun)和抗(kang)爆裂性(xing)極好,既耐高(gao)溫又抗(kang)奇寒,難怪在(zai)(zai)汽車(che)、航空(kong)、鐵路、電子技術、國防工(gong)業等(deng)部門,到處可見(jian)到釩(fan)(fan)(fan)的(de)蹤跡(ji)。此外,釩(fan)(fan)(fan)的(de)氧化物(wu)已成為化學工(gong)業中最佳催(cui)化劑之(zhi)一,有“化學面包”之(zhi)稱(cheng)。主要用于制造(zao)高(gao)速(su)切(qie)削鋼(gang)(gang)(gang)(gang)及其(qi)他合金鋼(gang)(gang)(gang)(gang)和催(cui)化劑。把釩(fan)(fan)(fan)摻進(jin)鋼(gang)(gang)(gang)(gang)里,可以制成釩(fan)(fan)(fan)鋼(gang)(gang)(gang)(gang)。釩(fan)(fan)(fan)鋼(gang)(gang)(gang)(gang)比(bi)普通鋼(gang)(gang)(gang)(gang)結構更緊密,韌(ren)性(xing)、彈(dan)(dan)性(xing)與機械強度更高(gao)。釩(fan)(fan)(fan)鋼(gang)(gang)(gang)(gang)制的(de)穿甲彈(dan)(dan),能夠射穿40厘米厚的(de)鋼(gang)(gang)(gang)(gang)板。但是,在(zai)(zai)鋼(gang)(gang)(gang)(gang)鐵工(gong)業上,并不是把純的(de)金屬釩(fan)(fan)(fan)加(jia)到鋼(gang)(gang)(gang)(gang)鐵中制成釩(fan)(fan)(fan)鋼(gang)(gang)(gang)(gang),而是直接采用含釩(fan)(fan)(fan)的(de)鐵礦煉成釩(fan)(fan)(fan)鋼(gang)(gang)(gang)(gang)。
釩具有(you)眾多(duo)優(you)異(yi)的(de)(de)(de)物理性能(neng)和(he)化學(xue)性能(neng),因(yin)而釩的(de)(de)(de)用(yong)(yong)(yong)途(tu)十分廣泛,有(you)金(jin)屬“維(wei)生素”之稱。最初的(de)(de)(de)釩大(da)多(duo)應(ying)(ying)用(yong)(yong)(yong)于鋼鐵,通過細化鋼的(de)(de)(de)組織和(he)晶粒,提高晶粒粗化溫度(du),從而起到增加鋼的(de)(de)(de)強度(du)、韌性和(he)耐(nai)磨(mo)性。后(hou)來,人(ren)們(men)逐漸(jian)又發現了釩在(zai)鈦合金(jin)中的(de)(de)(de)優(you)異(yi)改(gai)良作(zuo)用(yong)(yong)(yong),并應(ying)(ying)用(yong)(yong)(yong)到航空航天領域(yu),從而使得航空航天工業取得了突(tu)破性的(de)(de)(de)進(jin)展(zhan)。隨(sui)著(zhu)科(ke)學(xue)技術水平的(de)(de)(de)飛躍發展(zhan),人(ren)類對新材料的(de)(de)(de)要求日益提高。釩在(zai)非鋼鐵領域(yu)的(de)(de)(de)應(ying)(ying)用(yong)(yong)(yong)越來越廣泛,其范(fan)圍涵蓋了航空航天、化學(xue)、電池、顏料、玻璃、光學(xue)、醫藥等眾多(duo)領域(yu)。
釩(fan)(fan)(fan)“現代(dai)工(gong)業的味精(jing)”,是發(fa)展現代(dai)工(gong)業、現代(dai)國防和現代(dai)科學技術不可缺(que)少的重要材料。釩(fan)(fan)(fan)在冶金業中用量(liang)最(zui)大(da)。從(cong)世(shi)界(jie)范圍來看,釩(fan)(fan)(fan)在鋼鐵工(gong)業中的消耗量(liang)占其生產總量(liang)的85%。與(yu)此(ci)同時,釩(fan)(fan)(fan)在化工(gong)、釩(fan)(fan)(fan)電(dian)池、航(hang)空航(hang)天等(deng)其它領域的應用也在不斷擴展,且具有(you)良(liang)好發(fa)展前景。
釩在(zai)鋼(gang)鐵(tie)工業中主要(yao)用作合金添加(jia)劑,鋼(gang)鐵(tie)工業的(de)(de)發展(zhan)變化(hua)對(dui)預測釩的(de)(de)需(xu)求至關重要(yao)。也(ye)就是說(shuo),鋼(gang)鐵(tie)對(dui)釩的(de)(de)需(xu)求趨勢(shi)決定了釩工業的(de)(de)命運。
中國鋼(gang)產量大(da)約6億噸,平均每噸釩(fan)的消(xiao)費強度增加10g,折(zhe)合五(wu)氧化二釩(fan)約為(wei)1.1萬(wan)噸。而在美國,碳素鋼(gang)和(he)高(gao)強度低合金鋼(gang)是鋼(gang)鐵工業(ye)中釩(fan)用量最(zui)大(da)的鋼(gang)種,占鋼(gang)鐵工業(ye)釩(fan)用量的60%以上,其次是高(gao)合金鋼(gang)。
釩電池(chi)是發展勢頭(tou)強勁(jing)的(de)優秀綠(lv)色(se)環保蓄電池(chi)之一(制(zhi)造(zao)、使用及(ji)廢棄過程均(jun)不產生有害物質(zhi)),它具有特殊的(de)電池(chi)結構,可深(shen)度大電流(liu)密度放電;充電迅速;比(bi)能量高(gao);價格低廉;應用領域十(shi)分廣闊:如可作為(wei)大廈、機場、程控(kong)交換站備(bei)用電源;可作為(wei)太(tai)陽能等(deng)清潔發電系(xi)統的(de)配套儲能裝置;為(wei)潛艇、遠(yuan)洋輪船提供(gong)電力以及(ji)用于(yu)電網(wang)調峰等(deng)。
釩電(dian)(dian)池(chi)(chi)成本(ben)與(yu)鉛酸(suan)電(dian)(dian)池(chi)(chi)相近,它(ta)還可(ke)制(zhi)備(bei)兆瓦級(ji)電(dian)(dian)池(chi)(chi)組,大(da)功率(lv)長時(shi)間提供電(dian)(dian)能(neng),因此(ci)釩電(dian)(dian)池(chi)(chi)在(zai)大(da)規模(mo)(mo)儲能(neng)領(ling)域(yu)具有鋰離(li)子電(dian)(dian)池(chi)(chi)、鎳氫電(dian)(dian)池(chi)(chi)不可(ke)比(bi)擬(ni)的(de)(de)性價比(bi)優勢。釩電(dian)(dian)池(chi)(chi)生(sheng)產工藝(yi)簡單,價格(ge)經濟,電(dian)(dian)性能(neng)優異,與(yu)制(zhi)造(zao)復雜、價格(ge)昂貴的(de)(de)燃料電(dian)(dian)池(chi)(chi)相比(bi),無論(lun)是在(zai)大(da)規模(mo)(mo)儲能(neng)還是電(dian)(dian)動汽(qi)車動力電(dian)(dian)源的(de)(de)應用前景(jing)方面,都更具競爭(zheng)實力。
與其(qi)他化(hua)學電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)源(yuan)相比,釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)具有明(ming)顯的(de)(de)(de)優越性(xing)(xing),主(zhu)要優點如下:1、功率(lv)大(da):通(tong)(tong)過(guo)(guo)(guo)(guo)(guo)(guo)增(zeng)(zeng)加(jia)單片電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)數量(liang)(liang)(liang)和電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)面積,即(ji)可(ke)增(zeng)(zeng)加(jia)釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)功率(lv),美國商業(ye)化(hua)示范運行(xing)的(de)(de)(de)釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)功率(lv)已達(da)(da)6兆瓦(wa)。2、容量(liang)(liang)(liang)大(da):通(tong)(tong)過(guo)(guo)(guo)(guo)(guo)(guo)任(ren)意增(zeng)(zeng)加(jia)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)的(de)(de)(de)體積,即(ji)可(ke)任(ren)意增(zeng)(zeng)加(jia)釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)量(liang)(liang)(liang),可(ke)達(da)(da)吉(ji)瓦(wa)時(shi)以上;通(tong)(tong)過(guo)(guo)(guo)(guo)(guo)(guo)提高(gao)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)的(de)(de)(de)濃度(du)(du)(du),即(ji)可(ke)成(cheng)(cheng)倍增(zeng)(zeng)加(jia)釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)量(liang)(liang)(liang)。3、效(xiao)率(lv)高(gao):由(you)于釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)催化(hua)活性(xing)(xing)高(gao),且正、負(fu)(fu)(fu)極(ji)活性(xing)(xing)物(wu)(wu)質分別存儲在正、負(fu)(fu)(fu)極(ji)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)儲槽中,避(bi)免了正、負(fu)(fu)(fu)極(ji)活性(xing)(xing)物(wu)(wu)質的(de)(de)(de)自放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)消耗,釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)充(chong)(chong)放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)能量(liang)(liang)(liang)轉(zhuan)換(huan)效(xiao)率(lv)高(gao)達(da)(da)75%以上,遠(yuan)高(gao)于鉛(qian)酸(suan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)45%。4、壽(shou)命(ming)長(chang):由(you)于釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)正、負(fu)(fu)(fu)極(ji)活性(xing)(xing)物(wu)(wu)質只(zhi)分別存在于正、負(fu)(fu)(fu)極(ji)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)中,充(chong)(chong)放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)時(shi)無其(qi)它(ta)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)常(chang)有的(de)(de)(de)物(wu)(wu)相變(bian)化(hua),可(ke)深(shen)度(du)(du)(du)放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)而不損(sun)傷(shang)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi),電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)使用壽(shou)命(ming)長(chang)。商業(ye)化(hua)示范運行(xing)時(shi)間最長(chang)的(de)(de)(de)釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)模(mo)塊已正常(chang)運行(xing)超過(guo)(guo)(guo)(guo)(guo)(guo)9年(nian),充(chong)(chong)放循環壽(shou)命(ming)超過(guo)(guo)(guo)(guo)(guo)(guo)18000次,遠(yuan)遠(yuan)高(gao)于固定型(xing)鉛(qian)酸(suan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)的(de)(de)(de)1000次。5、響(xiang)應速(su)度(du)(du)(du)快(kuai):釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)堆里(li)充(chong)(chong)滿電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)可(ke)在瞬(shun)間啟動,在運行(xing)過(guo)(guo)(guo)(guo)(guo)(guo)程中充(chong)(chong)放電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)狀(zhuang)態(tai)切換(huan)只(zhi)需(xu)(xu)要0.02秒(miao),響(xiang)應速(su)度(du)(du)(du)1毫秒(miao)。6、可(ke)瞬(shun)間充(chong)(chong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian):通(tong)(tong)過(guo)(guo)(guo)(guo)(guo)(guo)更換(huan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)可(ke)實現釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)瞬(shun)間充(chong)(chong)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)。7、安全性(xing)(xing)高(gao):釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)無潛(qian)在的(de)(de)(de)爆炸或著火(huo)危險(xian),即(ji)使將正、負(fu)(fu)(fu)極(ji)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)混(hun)合也無危險(xian),只(zhi)是電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)解液(ye)(ye)(ye)溫度(du)(du)(du)略(lve)有升高(gao)。8、成(cheng)(cheng)本(ben)低(di):除(chu)離子膜外,釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)部件多為廉價(jia)的(de)(de)(de)碳(tan)材料(liao)、工程塑(su)料(liao),材料(liao)來源(yuan)豐富(fu),易回收(shou),不需(xu)(xu)要貴金(jin)屬作電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)極(ji)催化(hua)劑,成(cheng)(cheng)本(ben)低(di)。9、釩(fan)(fan)(fan)(fan)(fan)電(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)(chi)(chi)(chi)(chi)(chi)(chi)選址自由(you)度(du)(du)(du)大(da),可(ke)全自動封閉運行(xing),無污染,維護(hu)簡(jian)單,運營成(cheng)(cheng)本(ben)低(di)。
釩(fan)(fan)(fan)(fan)是(shi)人(ren)體中(zhong)的(de)(de)(de)微量元素(su)在(zai)人(ren)體內(nei)(nei)含量大約為(wei)25mg,在(zai)體液pH4~8條(tiao)件下釩(fan)(fan)(fan)(fan)的(de)(de)(de)主要形式為(wei)VO3-,即(ji)亞釩(fan)(fan)(fan)(fan)酸(suan)離(li)子;另一(yi)為(wei)+5價氧化形式VO43-,即(ji)正(zheng)釩(fan)(fan)(fan)(fan)酸(suan)離(li)子。由于(yu)生(sheng)物(wu)效應(ying)相(xiang)似(si),一(yi)般釩(fan)(fan)(fan)(fan)酸(suan)鹽統指(zhi)這(zhe)兩種+5價氧化離(li)子。VO3-經離(li)子轉運(yun)系(xi)統或(huo)自由進(jin)入(ru)(ru)細(xi)胞(bao),在(zai)胞(bao)內(nei)(nei)被還原型(xing)谷胱甘肽還原成(cheng)VO2+(+4價氧化態),即(ji)氧釩(fan)(fan)(fan)(fan)根離(li)子(vanadyl)。由于(yu)磷(lin)酸(suan)和(he)Mg2+離(li)子在(zai)細(xi)胞(bao)內(nei)(nei)廣泛存(cun)在(zai)VO-3與(yu)磷(lin)酸(suan)結(jie)構相(xiang)似(si),VO2+與(yu)Mg2+大小(xiao)相(xiang)當(離(li)子半徑分(fen)別為(wei)160pm和(he)165pm),因而二者就有可(ke)能通過(guo)與(yu)磷(lin)酸(suan)和(he)Mg2+競(jing)爭結(jie)合配體干擾細(xi)胞(bao)的(de)(de)(de)生(sheng)化反應(ying)過(guo)程(cheng)。例(li)如,抑制ATP水解酶、核糖核酸(suan)酶、磷(lin)酸(suan)果糖激酶、磷(lin)酸(suan)甘油醛激酶、6-磷(lin)酸(suan)葡萄糖酶、磷(lin)酸(suan)酪氨酸(suan)蛋白激酶。所以,釩(fan)(fan)(fan)(fan)進(jin)入(ru)(ru)細(xi)胞(bao)后具有廣泛的(de)(de)(de)生(sheng)物(wu)學效應(ying)。釩(fan)(fan)(fan)(fan)化合物(wu)又具有合成(cheng)相(xiang)對(dui)容易、價格較低廉的(de)(de)(de)優勢,因此研究釩(fan)(fan)(fan)(fan)化合物(wu)的(de)(de)(de)降壓機(ji)制有利于(yu)對(dui)釩(fan)(fan)(fan)(fan)的(de)(de)(de)開發和(he)利用。
國(guo)(guo)內外對釩化(hua)合(he)物(wu)的(de)(de)研(yan)究已有(you)20多(duo)年的(de)(de)歷史,早期多(duo)集中在釩化(hua)合(he)物(wu)降(jiang)糖作用的(de)(de)研(yan)究,也有(you)報(bao)道(dao)釩能舒張豬(zhu)的(de)(de)離(li)體冠狀動脈(mo)。近期國(guo)(guo)外有(you)些研(yan)究開始用釩化(hua)合(he)物(wu)治(zhi)療(liao)原發(fa)性高血壓(ya)大(da)鼠,已經取到肯定的(de)(de)實驗結果(guo)。有(you)報(bao)道(dao)認為(wei)BMOV可以降(jiang)低(di)SHR的(de)(de)高胰島素(su)血癥和(he)高血壓(ya)。另有(you)學者采(cai)用SHR和(he)WKY大(da)鼠對比(bi)探討(tao)釩化(hua)合(he)物(wu)對血壓(ya)的(de)(de)藥物(wu)療(liao)效,結果(guo)可見釩化(hua)合(he)物(wu)使收縮壓(ya)降(jiang)低(di)(149±3/mmHg,非治(zhi)療(liao)組(zu)184±3mmHgP<0.0001)。
釩(fan)(fan)是(shi)正常(chang)生長(chang)可能必需(xu)的(de)礦物質(zhi),釩(fan)(fan)有(you)多種(zhong)價態(tai)(tai)(tai),有(you)生物學(xue)意義的(de)是(shi)四價和五價態(tai)(tai)(tai)。四價態(tai)(tai)(tai)釩(fan)(fan)為(wei)氧(yang)釩(fan)(fan)基(ji)陽離(li)子,易與蛋(dan)白質(zhi)結合結合形(xing)成(cheng)復(fu)合物,而(er)防(fang)止(zhi)被氧(yang)化(hua)(hua)。五價態(tai)(tai)(tai)釩(fan)(fan)為(wei)氧(yang)釩(fan)(fan)基(ji)陽離(li)子,易與其他生物物質(zhi)結合形(xing)成(cheng)復(fu)合物,在許(xu)多生化(hua)(hua)過(guo)程中(zhong),釩(fan)(fan)酸(suan)(suan)根能與磷酸(suan)(suan)根競爭,或(huo)取代磷酸(suan)(suan)根。釩(fan)(fan)酸(suan)(suan)鹽以被維生素(su)C、谷(gu)胱甘肽或(huo)NADH還原。其在人體健(jian)康方(fang)面(mian)的(de)作用,營養學(xue)界(jie),醫(yi)學(xue)界(jie)至今仍(reng)不是(shi)很清楚,仍(reng)處在進一步發掘的(de)過(guo)程中(zhong),但可以確定(ding),釩(fan)(fan)有(you)重要作用。一般認為(wei),它可能有(you)助(zhu)于防(fang)止(zhi)膽固醇(chun)蓄積(ji)、降低過(guo)高的(de)血糖、防(fang)止(zhi)齲(qu)齒、幫助(zhu)制造紅血球等。每天會經(jing)尿液(ye)流失(shi)部分釩(fan)(fan)。
釩(fan)(fan)在(zai)人體(ti)內(nei)(nei)含(han)量(liang)(liang)極低(di),體(ti)內(nei)(nei)總量(liang)(liang)不足(zu)1mg。主要(yao)分(fen)布于內(nei)(nei)臟,尤(you)其(qi)是肝、腎、甲狀腺等部位,骨組(zu)織中含(han)量(liang)(liang)也較高。人體(ti)對釩(fan)(fan)的正常需要(yao)量(liang)(liang)為100μg/d。
釩(fan)(fan)(fan)在(zai)胃腸吸收(shou)率僅5%,其吸收(shou)部位主要在(zai)上消化(hua)道。此(ci)外環(huan)境中的釩(fan)(fan)(fan)可經皮膚和肺吸收(shou)入體中。血(xue)液中約95%的釩(fan)(fan)(fan)以離(li)子狀態(tai)(VO2+)與(yu)轉鐵蛋白結合(he)而(er)送輸,因此(ci)釩(fan)(fan)(fan)與(yu)鐵在(zai)體內可相互影響。
釩對骨和牙齒正(zheng)常(chang)發(fa)育及(ji)鈣化有關,能增強(qiang)牙對齲牙的抵抗力(li)。釩還可以促進(jin)(jin)糖(tang)代謝,刺激(ji)釩酸鹽(yan)依賴性NADPH氧化反(fan)應,增強(qiang)脂蛋白脂酶活性,加快腺(xian)苷酸環化酶活化和氨基酸轉化及(ji)促進(jin)(jin)紅(hong)細胞生長(chang)等作(zuo)用。因(yin)此釩缺乏時(shi)可出現(xian)牙齒、骨和軟(ruan)骨發(fa)育受阻。肝內(nei)磷脂含量少、營養(yang)不良性水(shui)腫及(ji)甲狀腺(xian)代謝異常(chang)等。
人類攝入的(de)(de)釩(fan)(fan)只(zhi)有(you)少部(bu)分(fen)被吸收(shou),估計吸收(shou)的(de)(de)釩(fan)(fan)不足攝入量的(de)(de)5%,大部(bu)分(fen)由(you)糞(fen)便排出(chu)。攝入的(de)(de)釩(fan)(fan)于(yu)小(xiao)腸與(yu)(yu)低分(fen)子量物(wu)質形成復合(he)物(wu),然后在血(xue)中與(yu)(yu)血(xue)漿運(yun)(yun)鐵蛋白結合(he),血(xue)中釩(fan)(fan)很快就運(yun)(yun)到各(ge)組織,通(tong)常大多組織每(mei)克(ke)濕重含釩(fan)(fan)量低于(yu)10ng。吸收(shou)入體(ti)內的(de)(de)80%-90%由(you)尿(niao)排出(chu),也可以(yi)通(tong)過(guo)膽(dan)汁排出(chu),每(mei)克(ke)膽(dan)汁含釩(fan)(fan)為0.55-1.85ng。
有實驗顯(xian)示(shi),釩調節(Nak)-ATP酶(mei)、調節磷酰轉移(yi)酶(mei)、腺(xian)苷酸(suan)環(huan)化(hua)酶(mei)、蛋白激酶(mei)類的輔因(yin)子,與(yu)體(ti)內激素,蛋白質,脂類代謝關系密切(qie)。可(ke)抑制年幼大鼠(shu)肝臟合成膽(dan)固(gu)醇。可(ke)能存在(zai)以下作(zuo)用:1.防止(zhi)因(yin)過(guo)熱而(er)疲勞和中暑。2.促進骨骼及牙(ya)齒生長(chang)。3.協(xie)助(zhu)脂肪代謝的正常化(hua)。4.預防心(xin)臟病(bing)突發。5.協(xie)助(zhu)神經和肌肉(rou)的正常運作(zuo)。
人(ren)的(de)(de)(de)膳(shan)食(shi)(shi)中(zhong)(zhong)(zhong)每(mei)天(tian)可(ke)提供不(bu)足30μg的(de)(de)(de)釩,多為(wei)15μg,因此考慮每(mei)天(tian)從膳(shan)食(shi)(shi)中(zhong)(zhong)(zhong)攝取(qu)10μg釩就可(ke)以滿(man)足需要。一般不(bu)需要特別補充;需要提醒(xing)的(de)(de)(de)是,攝取(qu)合成的(de)(de)(de)釩容易引起中(zhong)(zhong)(zhong)毒;另外吸煙會降低(di)釩的(de)(de)(de)吸收。
釩在體內不易蓄積(ji),因而由(you)食(shi)物(wu)攝(she)入(ru)引起的中毒(du)十分罕見,但每(mei)天攝(she)入(ru)10mg以(yi)上或每(mei)克食(shi)物(wu)中含釩10-20微克,可發(fa)生(sheng)中毒(du)。通常可出現(xian)生(sheng)長緩慢(man)、腹瀉、攝(she)入(ru)量減少(shao)和死亡(wang)。
最被(bei)認(ren)(ren)可(ke)的(de)釩(fan)缺(que)乏(fa)表(biao)現來(lai)自于1987年報道的(de)對(dui)山羊(yang)和(he)大鼠(shu)的(de)研究(jiu)(jiu),釩(fan)缺(que)乏(fa)的(de)山羊(yang)表(biao)現出流產率(lv)增加(jia)和(he)產奶量降低。大鼠(shu)實驗中,釩(fan)缺(que)乏(fa)引起生長(chang)抑(yi)制,甲(jia)狀腺重(zhong)(zhong)量與體重(zhong)(zhong)的(de)比率(lv)增加(jia)以及血(xue)漿甲(jia)狀腺激素(su)濃度(du)的(de)變化。對(dui)于人體缺(que)乏(fa)癥研究(jiu)(jiu)尚不明確,有的(de)研究(jiu)(jiu)認(ren)(ren)為它的(de)缺(que)乏(fa)可(ke)能(neng)(neng)會導致心血(xue)管(guan)及腎臟疾病、傷口再生修復能(neng)(neng)力減退和(he)新生兒死(si)亡(wang)。
釩(fan)在(zai)天然(ran)水(shui)中(zhong)的(de)濃度很低,一(yi)般河水(shui)中(zhong)為0.01~20ppb,平(ping)均為1ppb。海水(shui)含釩(fan)量為0.9~2.5ppb。盡(jin)管水(shui)體(ti)中(zhong)可溶性(xing)(xing)的(de)釩(fan)含量很低,但是水(shui)中(zhong)懸浮(fu)(fu)物(wu)含釩(fan)量是很高的(de)。懸浮(fu)(fu)物(wu)的(de)沉積導致(zhi)水(shui)中(zhong)釩(fan)向底(di)質(zhi)遷移(yi),并使水(shui)體(ti)得到凈化。土(tu)(tu)(tu)壤(rang)(rang)中(zhong)的(de)釩(fan)主要以VO3-陰離子狀(zhuang)態存在(zai)。土(tu)(tu)(tu)壤(rang)(rang)的(de)氧化性(xing)(xing)越高、堿(jian)性(xing)(xing)越大,釩(fan)越易形成(cheng)VO3-離子。當土(tu)(tu)(tu)壤(rang)(rang)的(de)酸度增(zeng)大時(shi),VO3-離子易轉變(bian)成(cheng)多釩(fan)酸根復合(he)陰離子。它們都(dou)容易被(bei)粘(zhan)土(tu)(tu)(tu)和土(tu)(tu)(tu)壤(rang)(rang)膠(jiao)體(ti)及腐殖質(zhi)固定而(er)失去活(huo)性(xing)(xing),釩(fan)在(zai)土(tu)(tu)(tu)壤(rang)(rang)中(zhong)的(de)遷移(yi)性(xing)(xing)較弱。
金屬釩(fan)(fan)的毒性很低。釩(fan)(fan)化(hua)合(he)物(釩(fan)(fan)鹽)對人和動(dong)物具有毒性,其毒性隨化(hua)合(he)物的原子價增加(jia)和溶解度(du)的增大而(er)增加(jia),如五氧(yang)化(hua)二釩(fan)(fan)為(wei)高毒,可引起(qi)呼(hu)吸系(xi)統(tong)、神經系(xi)統(tong)、胃(wei)腸和皮膚的改變(bian)。
皮膚接觸:脫(tuo)(tuo)去污(wu)染的衣著,用肥皂(zao)水(shui)及(ji)清水(shui)徹底沖洗。眼(yan)睛接觸:立即翻開上下眼(yan)瞼,用流(liu)動清水(shui)沖洗15分鐘。就醫。吸入:脫(tuo)(tuo)離現場至(zhi)空氣新(xin)鮮(xian)處,用水(shui)漱洗鼻咽(yan)部的粉塵。就醫。食入:誤(wu)服者就醫。對(dui)癥治療。
儲存(cun)于陰涼(liang)、通風的庫房。遠離火種(zhong)、熱源(yuan)。應(ying)(ying)與氧化(hua)劑(ji)、酸類、食用化(hua)學品(pin)分開存(cun)放,切忌混儲。配(pei)備(bei)相應(ying)(ying)品(pin)種(zhong)和(he)數量的消防器材。儲區應(ying)(ying)備(bei)有合適的材料收容泄漏(lou)物。